Hollowing out MOFs: hierarchical micro- and mesoporous MOFs with tailorable porosity via selective acid etching† †This work was supported by the Institute for Basic Science (IBS) [IBS-R007-D1]. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02886e Click here for additional data file.

Metal organic framework synthesis in the presence of surfactants: towards hierarchical MOFs?† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c4ce02324b Click here for additional data file.

Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c4sc03217a Click here for additional data file.

Competitive coordination strategy for the synthesis of hierarchical-pore metal–organic framework nanostructures† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02272c Click here for additional data file.

Metal–organic frameworks (MOFs) usually have micropores smaller than 2 nm, which may restrict their applications in some cases. Hierarchical-pore MOFs (H-MOFs) are a new family of MOF materials, possessing both microand mesopores to address this problem. Here we demonstrate a competitive coordination strategy for the synthesis of H-MOF nanostructures, such as two-dimensional (2D) H-MOF nanoshee...

Self-disproportionation of enantiomers of thalidomide and its fluorinated analogue via gravity-driven achiral chromatography: mechanistic rationale and implications† †Electronic supplementary information (ESI) available. CCDC 1009504, 1009505, 1009506, 1009507, 1009508, 1009509. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03047h Click here for additional data file. Click here for additional data file.

Department of Nanopharmaceutical Scienc Nagoya Institute of Technology, Gokiso, Sho [email protected]; Fax: +81-52-735-754 Department of Life Science and Medical Wakamatsu-cho 2-2, Shinjuku-ku, Tokyo 16 Consolidated Research Institute for Advan University (ASMeW), Waseda-tsurumaki-cho † Electronic supplementary information ( 1009506, 1009507, 1009508, 1009509. For other electronic format se...

Persistent four-coordinate iron-centered radical stabilized by π-donation† †Electronic supplementary information (ESI) available: Experimental, crystallographic, computational details, and crystal data for 2, 4, 5 and 8. CCDC 1057111–1057113 and 1425703. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02601f Click here for additional data file. Click here for additional data file.

Institute for Materials Chemistry and Kasugakoen, Kasuga, Fukuoka 816-8580, Ja Department of Chemistry, Graduate Schoo Sendai 980-8578, Japan Institute for Materials Chemistry and En Fukuoka 819-0395, Japan CREST, Japan Science and Technology Fukuoka 816-8580, Japan † Electronic supplementary informati crystallographic, computational details, a 1057111–1057113 and 1425703. For ESI other electro...